The team at the Helmholz-Zentrum Berlin (HZB) and Drexel University in the US have found that new versions of the MXene 2D material can deliver a capacitance of 1100 mF/cm2, 56 per cent higher than previous versions.
MXenes, developed at Drexel, are nanosheets of Ti3C2Tx molecules that form a two-dimensional network similar to graphene. While titanium (Ti) and carbon (C) are elements, Tx denotes various chemical groups that seal the surface, for example OH groups. MXenes are highly conductive materials with hydrophilic surfaces. In water they form dispersions that resemble black ink.
Ti3C2Tx can store as much energy as a battery, but can be charged or discharged within tenths of a second. While similarly fast (or faster) supercapacitors absorb their energy by electrostatic adsorption of electrical charges, the energy in MXenes is stored in chemical bonds on their surfaces. This type of energy storage is much more efficient. In collaboration with the group around Yuri Gogotsi at Drexel University, HZB scientists Dr. Tristan Petit and Ameer Al-Temimy have now used soft X-ray absorption spectroscopy for the first time to study MXene samples at the LiXEdrom and X-PEEM experimental stations. They were able to analyse the chemical environment of MXene surface groups in vacuum, but also directly in water.
They examined samples of pure MXene and MXene with embedded urea molecules and found dramatic differences: The presence of urea molecules significantly changes the electrochemical properties of MXene. The area capacity increased to 1100 mF/cm2, which is 56 percent higher than that of similarly prepared pure Ti3C2Tx electrodes.
The XAS analyses performed at the electron synchrotron at BESSY II showed that the surface chemistry is changed by the presence of the urea molecules. “At X-PEEM we could also observe the oxidation state of the Ti atoms on the Ti3C2Tx surfaces. This oxidation state increased due to the presence of urea, which could facilitate the storage of more energy,” says Ameer Al-Temimy, who carried out the measurements as part of his doctoral thesis. This discovery should mean More storage capacity in less space – a property that is highly welcome in electronics.
Helmholtz Zentrum Berlin: https://www.helmholtz-berlin.de/index_en.html
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