Charged holes in graphene offer energy storage boost
The research, published online in the journal Nano Letters, may provide a better understanding of how to improve the energy storage ability of capacitors which charge and discharge rapidly, and are more useful for quick large bursts of energy, such as in camera flashes and power plants. The ability of capacitors to rapidly charge and discharge is an advantage compared with the long charge time of batteries. However, the problem with capacitors is that they store less energy than batteries.
How can the energy storage of a capacitor be improved? One approach by researchers in the lab of mechanical engineering professor Prabhakar Bandaru at the Jacobs School of Engineering at UC San Diego was to introduce more charge into a capacitor electrode using graphene as a model material for their tests. The principle is that increased charge leads to increased capacitance, which translates to increased energy storage.
Making a perfect carbon nanotube structure – one without defects, which are holes corresponding to missing carbon atoms – is next to impossible. Rather than avoiding defects, the researchers in Bandaru’s lab figured out a practical way to use them instead.
"I was motivated from the point of view that charged defects may be useful for energy storage," explained Bandaru.
Zigzag and armchair defects in graphene.
"It was exciting to show that we can introduce extra capacitance by introducing charged defects, and that we could control what kind of charged defect we could introduce into a material," said Rajaram Narayanan, a graduate student in professor Bandaru’s research group and first author of the study.
Using Raman spectroscopy and electrochemical measurements, the team was able to characterize the types of defects that argon plasma processing introduced into the graphene lattices. The results revealed the formation of extended defects known as ‘armchair’ and ‘zigzag’ defects, which are named based on the configurations of the missing carbon atoms.
Additionally, electrochemical studies helped the team discover a new length scale that measures the distance between charges. "This new length scale will be important for electrical applications, since it can provide a basis for how small we can make electrical devices," said Bandaru.
Reference: R. Narayanan, H. Yamada, M. Karakaya, R. Podila, A. M. Rao, and P. R. Bandaru. Modulation of the Electrostatic and Quantum Capacitances of Few Layered Graphenes through Plasma Processing. Nano Letters 2015. DOI: 10.1021/acs.nanolett.5b00055
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