Differentiate or loose! Yole’s analysis on LED phosphors and QDs
In its recent report “Phosphors & Quantum Dots 2017 – LED Downconverters for Lighting & Displays”, Yole highlights that most of those companies do not have any elements of differentiation, be it on performance or manufacturing cost that could allow them to survive in the mid and long term. For most phosphor suppliers, the name of the game is to keep decreasing costs as volume increase and revenue remain essentially flat.
On the IP front, key patents held by Nichia and Osram have started expiring in 2017 and will continue to do so in 2018. While both companies have since built on those patents and created broad families of intellectual property (IP), it will become much more difficult for them to prevent competitors from using garnet phosphors in their LED packages.

(source: Phosphors & Quantum Dots 2017 –
LED Downconverters for Lighting & Displays,
Yole Développement.)
As a result, phosphor families such as silicates and yellow nitrides (LYSN) are expected to lose market share as LED packages transition to garnets. The switch will especially affect silicates, which are perceived to have lower performance than yttrium aluminum garnet (YAG) and other garnets.
However, some of the most recent silicate compositions developed by tier-1 suppliers are now matching YAG performance but come at a premium price. Leading phosphor suppliers with a strong focus on silicate materials must therefore diversify their portfolio. They need to create new silicate compositions with unique features to meet specific demands in various high added value lighting applications.
LYSN might fare better in the long term. Yellow nitrides have exhibited steady and continuous performance improvement since entering the market in 2010. The material is already matching garnet performance in most aspects and, being less mature, still offers significant room for improvement. Attractive features of yellow nitride include a lower infrared tail that could translate to higher efficiency compared to YAG. Leaders in nitride phosphors could therefore find a new growth driver as the red nitride market reaches saturation.
Quantum dots now challenging phosphors
For wide color gamut (WCG) TVs and monitors, potassium fluorosilicates (PFS/KSF) and phosphors in general are now being challenged by quantum dots (QDs), which are gaining rapid acceptance, notes Virey. In 2017, QDs can be found in 47% of WCG TVs. QDs deliver the best color gamut and higher efficiency, allowing LCD TV manufacturers to deliver improved image quality rivaling that of OLEDs in many regards without having to invest in new fabs.
Yole sees QDs set to dominate the rapidly emerging market for high performance WCG TVs and monitors. However, the emergence of a narrow-band green phosphor with the appropriate center wavelength could challenge this dominance and disrupt the market.

(source: Phosphors & Quantum Dots 2017 –
LED Downconverters for Lighting & Displays,
Yole Développement.)
QDs have also made significant progress toward “on-chip” configurations. Lumileds and Pacific Light Technology have demonstrated the first commercial grade, high color rendering index (CRI) mid-power LEDs based on high-stability QDs. However, more work is needed to reduce the cadmium content to levels meeting international regulations on heavy metals.
The technology could be ready for 2019 but whether or not LED makers will be willing to adopt a downconverter solution containing cadmium will depend on the performance gap that those QD-based LEDs will deliver compared to traditional phosphors, estimates the analyst.
In displays new phosphor compositions have also rapidly gained market share. After the rise of green silicon aluminum oxygen and nitrogen compounds (SiAlONs), red nitrides are being displaced by PFS which has already captured a 34% share in WCG TVs.
After five years of cut-throat competition that has driven prices to levels that nobody would have believed sustainable just a few years back, phosphor prices halted their free fall in 2016.
The most mature compositions such as garnets have reached bottom. But nitride, oxynitride and KSF still have room for significant decline that will offset modest volume growth as the LED market reaches saturation toward the end of the decade.
In this environment, Yole expects further rationalization of the industry landscape with tier-2 and -3 companies in China exiting the business, mostly due to their lack of differentiation.
Yet, a handful of domestic players such as Grirem or Yuji Science are emerging as long term credible competitors alongside established leaders such as Intematix and Mitsubishi Chemical. The LED industry still has unmet needs in terms of phosphors and new trends and applications such as high CRI lighting and human-centric lighting are generating new demands for efficiency and spectral engineering.
Companies able to develop and commercialize new narrow-band red and, to a lesser extent, green materials could last long-term if they can secure their innovations with strong intellectual property. Other needs, such as good cyan phosphors and red ceramics, could enable more companies, including new entrants, to succeed in this challenging market.
While price ranges for established compositions will narrow, Yole expects a significant gap between low end and top performers to persist. This will enable some suppliers to keep capturing significant added value through improved material performance, consistency, ability to deliver highly customized products and strong IP.
Yole Développement – www.yole.fr
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