Dual nanowire structure absorbs light efficiently

Technology News |
By eeNews Europe

The technique makes it possible to use different semiconductor materials for the different types of nanowires.

"We have succeeded in combining nanowires grown by the VLS (vapor-liquid-solid) and SAE (selective-area epitaxy) techniques onto the same platform. The difference compared with studies conducted previously on the same topic is that in the dual-type array the different materials do not grow in the same nanowire, but rather as separate wires on the same substrate," explained Docent Teppo .

The research results were published in the Nano Letters journal.

The fabrication process has many phases. First, gold nanoparticles are spread on a substrate. Next, the substrate is coated with silicon oxide, into which small holes are then patterned using electron beam lithography. In the first step of growth, (SAE), nanowires grow from where the holes are located, after which the silicon oxide is removed. In the second phase different types of nanowires are grown with the help of the gold nanoparticles (VLS). The researchers used metalorganic vapor phase epitaxy reactor in which the starting materials decompose at a high temperature, forming semiconductor compounds on the substrate.

"We managed to combine two growth methods into the same process," said doctoral candidate Joona-Pekko Kakko.

"We noticed in optical reflection measurements that light couples better to this kind of combination structure. For instance, a solar cell has less reflection and better absorption of light," pointed out Huhtio.

In addition to solar cells and LEDs, the researchers also see good applications in thermoelectric generators. 

Initially the substrate is prepared by depositing Au nanoparticles on it and covering it with a hole-patterned oxide. The first nanowires grow from these holes and after the oxide is removed, the other type of nanowires are grown via the deposited nanoparticles. The resulting dual-type array is presented on the electron micrograph on the right.

Nanowires are being researched, because semiconductor components that are currently in use need to be made smaller and more cost-effective. The nanowires made out of semiconductor materials are typically 1-10 micrometres in length, with diameters of 5-100 nanometres.

Reference: Joona-Pekko P. Kakko, Tuomas Haggrén, Veer Dhaka, Teppo Huhtio, Antti Peltonen, Hua Jiang, Esko Kauppinen, and Harri Lipsanen, Fabrication of Dual-Type Nanowire Arrays on a Single Substrate, Nano Lett., Article ASAP. DOI: 10.1021/nl504308x, Publication Date (Web): February 5, 2015, Link to the article

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