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Electrons go spiral with this organic semiconductor

Electrons go spiral with this organic semiconductor

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By Wisse Hettinga



This development could improve the efficiency of OLED displays in television and smartphone screens, or power next-generation computing technologies such as spintronics and quantum computing

TU Eindhoven reports:

Researchers, led by the University of Cambridge and the Eindhoven University of Technology, have created an organic semiconductor that forces electrons to move in a spiral pattern, which could improve the efficiency of OLED displays in television and smartphone screens, or power next-generation computing technologies such as spintronics and quantum computing.

The semiconductor they developed emits circularly polarised light—meaning the light carries information about the ‘left or right-handedness’ of electrons. The internal structure of most inorganic semiconductors, like silicon, is symmetrical, meaning electrons move through them without any preferred direction.

However, in nature, molecules often have a chiral (left- or right-handed) structure: like human hands, chiral molecules are mirror images of one another. Chirality plays an important role in biological processes like DNA formation, but it is a difficult phenomenon to harness and control in electronics.

Left: photo of our green OLED with schematic of circularly polarized photons. Photo: Seung-Je Woo - Middle: microscope image of the green-fluorescent ordered regions after crystallization in the OLED device. Image: Ritu Chowdhury - Right: schematic of the helical stacked structure of the organic semiconductor. Image: privately owned
Left: photo of our green OLED with schematic of circularly polarized photons. Photo: Seung-Je Woo – Middle: microscope image of the green-fluorescent ordered regions after crystallization in the OLED device. Image: Ritu Chowdhury – Right: schematic of the helical stacked structure of the organic semiconductor. Image: privately owned

Chiral semiconductors

By using molecular design tricks inspired by nature, the researchers were able to create a chiral semiconductor by nudging stacks of semiconducting molecules to form ordered right-handed or left-handed spiral columns. Their results are reported in the journal Science.

One promising application for chiral semiconductors is in display technology. Current displays often waste a significant amount of energy due to the way screens filter light. The chiral semiconductor developed by the researchers naturally emits light in a way that could reduce these losses, making screens brighter and more energy-efficient.

“When I started working with organic semiconductors, many people doubted their potential, but now they dominate display technology,” said Professor Sir Richard Friend from Cambridge’s Cavendish Laboratory, who co-led the research.

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