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Fool’s gold gives insight into potassium and sodium batteries

Fool’s gold gives insight into potassium and sodium batteries

Technology News |
By Christoph Hammerschmidt



“One of the biggest obstacles for sodium- and potassium-ion batteries has been that they tend to decay and degrade faster and hold less energy than alternatives,” said Matthew McDowell, an assistant professor in the George W. Woodruff School of Mechanical Engineering and the School of Materials Science and Engineering. “But we’ve found that’s not always the case,” he added.

The team looked at how three different ions — lithium, sodium, and potassium — reacted with particles of iron sulfide, also called pyrite or fool’s gold. As batteries charge and discharge, ions move in and out of the electrodes, changing the volume and often breaking them up. Because sodium and potassium ions are larger than lithium, they cause more significant degradation.

In their experiments, the reactions that occur inside a battery were directly observed inside an electron microscope, with the iron sulfide particles playing the role of a battery electrode. The researchers found that iron sulfide was more stable during reaction with sodium and potassium than with lithium, indicating that such a battery based on sodium or potassium could have a much longer life than expected.

The difference between how the different ions reacted was stark visually. When exposed to lithium, iron sulfide particles appeared to almost explode under the electron microscope. On the contrary, the iron sulfide expanded like a balloon when exposed to the sodium and potassium.

“We saw a very robust reaction with no fracture — something that suggests that this material and other materials like it could be used in these novel batteries with greater stability over time,” said Matthew Boebinger, a graduate student at Georgia Tech.

The study also casts doubt on the notion that large volume changes that occur during the electrochemical reaction are always a precursor to the fractures that causes electrode failure leading to battery degradation.


The researchers suggested that one possible reason for the difference in how the different ions reacted with the iron sulfide is that the lithium was more likely to concentrate its reaction along the particle’s sharp cube-like edges, whereas the reaction with sodium and potassium was more diffuse along all of the surface of the iron sulfide particle. As a result, the iron sulfide particle when reacting with sodium and potassium developed a more oval shape with rounded edges.

While there’s still more work to be done, the new research findings could help scientists design battery systems that use these types of novel materials.

“Lithium batteries are still the most attractive right now because they have the most energy density — you can pack a lot of energy in that space,” said McDowell. “Sodium and potassium batteries at this point don’t have more density, but they are based on elements a thousand times more abundant in the earth’s crust than lithium. So they could be much cheaper in the future, which is important for large scale energy storage — backup power for homes or the energy grid of the future.”

www.gatech.edu

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