Hybrid lead halide perovskites recycle light to boost efficiencies
By showing that they can also be optimized to recycle light, the latest study suggests that this could just be the beginning. Solar cells work by absorbing photons from the sun to create electrical charges, but the process also works in reverse, because when the electrical charges recombine, they can create a photon. The research shows that perovskite cells have the extra ability to re-absorb these regenerated photons – a process known as ‘photon recycling’ which creates a concentration effect inside the cell, as if a lens has been used to focus lots of light in a single spot.
According to the researchers, this ability to recycle photons could be exploited with relative ease to create cells capable of pushing the limits of energy efficiency in solar panels.
The latest study builds on an established collaboration, focusing on the use of the materials not only in solar cells but also in light-emitting diodes, and was carried out by the group of Richard Friend, Cavendish Professor of Physics and Fellow of St John’s College at the University of Cambridge. The research was undertaken in partnership with the team of Henry Snaith at the University of Oxford and Bruno Ehrler at the FOM Institute, AMOLF, Amsterdam.
“It is a massive demonstration of the quality of this material and opens the door to maximizing the efficiency of solar cells. The fabrication methods that would be required to exploit this phenomenon are not complicated, and that should boost the efficiency of this technology significantly beyond what we have been able to achieve until now,” said Felix Deschler, who is one of the corresponding authors of the study and works with a team studying perovskites at the Cavendish Laboratory.
Perovskite-based solar cells were first tested in 2012 and since then, researchers have made rapid progress in improving the efficiency with which these cells convert light into electrical energy. Recent experiments have produced power conversion efficiencies of about 20% – a figure already comparable with silicon cells.
By showing that perovskite-based cells can also recycle photons, the research suggests that they could reach efficiencies well beyond the 20% mark.
The study, which is reported in Science, involved shining a laser on to one part of a 500 nm-thick sample of lead-iodide perovskite. Perovskites emit light when they come into contact with it, so the team was able to measure photon activity inside the sample based on the light it emitted.
Close to where the laser light had shone on to the film, the researchers detected a near-infrared light emission. Crucially the emission was also detected further away from the point where the laser hit the sample, together with a second emission composed of lower-energy photons.
“The low-energy component enables charges to be transported over a long distance, but the high-energy component could not exist unless photons were being recycled,” said Luis Miguel Pazos Outón, a co-author on the study. “Recycling is a quality that materials like silicon simply don’t have. This effect concentrates a lot of charges within a very small volume. These are produced by a combination of incoming photons and those being made within the material itself, and that’s what enhances its energy efficiency.”
As part of the study, Pazos Outón also manufactured the first demonstration of a perovskite-based back-contact solar cell. The single cell proved capable of transporting an electrical current more than 50 micrometres away from the contact point with the laser which is a distance greater than the researchers had predicted and a direct result of multiple photon recycling events taking place within the sample.
The researchers now believe that perovskite solar cells, may be able to reach higher efficiencies than they have to date. “The fact that we were able to show photon recycling happening in our own cell, which had not been optimized to produce energy, is extremely promising,” said Richard Friend, a corresponding author. “If we can harness this it would lead to huge gains in terms of energy efficiency.”
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