Lithium batteries perform well at extreme temps
To achieve this, the researchers developed an electrolyte that is not only versatile and robust throughout a wide temperature range, but also compatible with a high energy anode and cathode. Such batteries, say the researchers, could allow electric vehicles in cold climates to travel farther on a single charge, and they could also reduce the need for cooling systems to keep the vehicles’ battery packs from overheating in hot climates.
“You need high temperature operation in areas where the ambient temperature can reach the triple digits and the roads get even hotter. In electric vehicles, the battery packs are typically under the floor, close to these hot roads,” says Zheng Chen, a professor of nanoengineering at the UC San Diego Jacobs School of Engineering and a senior author of a study on the research. “Also, batteries warm up just from having a current run through during operation. If the batteries cannot tolerate this warmup at high temperature, their performance will quickly degrade.”
In tests, the proof-of-concept batteries retained 87.5% and 115.9% of their energy capacity at -40° and 50°C (-40° and 122°F), respectively. They also had high Coulombic efficiencies of 98.2% and 98.7% at these temperatures, respectively, which means the batteries can undergo more charge and discharge cycles before they stop working.
The batteries are both cold and heat tolerant thanks to their electrolyte, which is made of a liquid solution of dibutyl ether mixed with a lithium salt. A special feature about dibutyl ether is that its molecules bind weakly to lithium ions – in other words, the electrolyte molecules can easily let go of lithium ions as the battery runs.
This weak molecular interaction, say the researchers, improves battery performance at sub-zero temperatures. Plus, dibutyl ether can easily take the heat because it stays liquid at high temperatures (it has a boiling point of 141 C, or 286 F).
The electrolyte is also compatible with a lithium-sulfur battery, which is a type of rechargeable battery that has an anode made of lithium metal and a cathode made of sulfur. Lithium-sulfur batteries are an essential part of next-generation battery technologies because they promise higher energy densities and lower costs, say the researchers.
They can store up to two times more energy per kilogram than today’s lithium-ion batteries—this could double the range of electric vehicles without any increase in the weight of the battery pack. Also, sulfur is more abundant and less problematic to source than the cobalt used in traditional lithium-ion battery cathodes.
However, both the cathode and anode of lithium-sulfur batteries are super reactive. Sulfur cathodes are so reactive that they dissolve during battery operation. This issue gets worse at high temperatures. And lithium metal anodes are prone to forming needle-like structures called dendrites that can pierce parts of the battery, causing it to short-circuit. As a result, lithium-sulfur batteries only last up to tens of cycles.
“If you want a battery with high energy density, you typically need to use very harsh, complicated chemistry,” says Chen. “High energy means more reactions are happening, which means less stability, more degradation. Making a high-energy battery that is stable is a difficult task itself—trying to do this through a wide temperature range is even more challenging.”
The dibutyl ether electrolyte developed by the researchers prevents these issues, even at high and low temperatures. The batteries they tested had much longer cycling lives than a typical lithium-sulfur battery.
“Our electrolyte,” says Chen, “helps improve both the cathode side and anode side while providing high conductivity and interfacial stability.”
The researchers also engineered the sulfur cathode to be more stable by grafting it to a polymer. This prevents more sulfur from dissolving into the electrolyte. Looing ahead, say the researchers, the next steps will include scaling up the battery chemistry, optimizing it to work at even higher temperatures and further extending cycle life.
For more, see “Solvent selection criteria for temperature-resilient lithium–sulfur batteries.”
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