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Nanosheet technology boosts energy storage dielectric capacitors

Nanosheet technology boosts energy storage dielectric capacitors

Technology News |
By Jean-Pierre Joosting



A research group led by Professor Minoru Osada at the Institute for Materials and Systems for Sustainability (IMaSS), Nagoya University in Japan, in collaboration with NIMS, has developed a nanosheet device with the highest energy storage performance yet seen. Their results were published in Nano Letters.

Innovations in energy storage technology are vital for the effective use of renewable energy and the mass production of electric vehicles. Current energy storage technology, such as lithium-ion batteries, has long charging times and problems, including electrolyte degradation, lifetime, and even unwanted ignition. One promising alternative is dielectric energy storage capacitors.

“Dielectric capacitors have many advantages, such as a short charging time of only a few seconds, long life, and high power density,” Osada said. However, the energy density of current dielectrics falls significantly short of meeting the increasing demands for electrical energy. Enhancing the energy density using nanosheet technology would help dielectric capacitors compete with other energy storage devices.  

Since the energy stored in a dielectric capacitor is related to the amount of polarization, the key to achieving high energy density is to apply as high an electric field as possible to a high dielectric constant material. However, existing materials are limited by the amount of electric field they can handle.  

To go beyond conventional dielectric research, the group used layers of nanosheets made of calcium, sodium, niobium, and oxygen with a perovskite crystal structure. “The perovskite structure is known as the best structure for ferroelectrics, as it has excellent dielectric properties such as high polarization,” Osada explains. “We found that by using this property, a high electric field could be applied to dielectric materials with high polarization and converted into electrostatic energy without loss, achieving the highest energy density ever recorded.” 

The findings of the research group confirmed that nanosheet dielectric capacitors achieved a 1-2 orders of magnitude higher energy density while maintaining the same high output density. Further, the nanosheet-based dielectric capacitor achieved a high energy density that maintained its stability over multiple cycles of use and was stable even at high temperatures up to 300°C.

“This achievement provides new design guidelines for the development of dielectric capacitors and is expected to apply to all-solid-state energy storage devices that take advantage of nanosheet technology features such as high energy density, high power density, short charging time of as little as a few seconds, long life, and high temperature stability,” Osada said. “Dielectric capacitors possess the ability to release stored energy in an extremely short time and create an intense pulsed voltage or current. These features are useful in many pulsed-discharge and power electronic applications. In addition to hybrid electric vehicles, they would also be useful in high-power accelerators and high-power microwave devices.” 

Image: Ultrahigh energy storage in 2D high-κ Perovskites. Credit Minoru Osada, Nagoya University.

Paper: https://doi.org/10.1021/acs.nanolett.3c00079

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