Perovskite-based LEDs boast near 100% internal quantum efficiencies

Perovskite-based LEDs boast near 100% internal quantum efficiencies

Technology News |
By eeNews Europe

The perovskite–polymer bulk heterostructure light-emitting diodes described in a paper titled “High-efficiency perovskite–polymer bulk heterostructure light-emitting diodes” and published in Nature Photonics is reported to achieve light-emission efficiencies close to the theoretical efficiency limit of thin-film OLEDs. Because non-radiative recombination pathways are effectively eliminated in this structure, the perovskite-polymer bulk heterostructure LEDs exhibited external quantum efficiencies of up to 20.1 percent (at current densities of 0.1 to 1mA cm−2).

What the researchers observed was that when shining an ultrafast laser on the structures, pairs of electric charges moved from the 2D regions to the 3D regions within 1ps, significantly faster than previous layered perovskite structures used in LEDs. The separate charges in the 3D regions then recombined to emit light at high efficiency.
“Since the energy migration from 2D regions to 3D regions happens so quickly, and the charges in the 3D regions are isolated from the defects by the polymer, these mechanisms prevent the defects from getting involved, thereby preventing energy loss,” explained researcher Dawei Di.
The researchers engineered the perovskite layer in the LEDs to show close to 100 percent internal luminescence efficiency. The perovskite materials were the same as those used to make highly efficient solar cells.

Compared to OLEDs, the perovskite-based LEDs can be made at much lower costs and can be tuned to emit light across the VIS and NIR spectra with high colour purity. However, while perovskite-based LEDs are comparable to OLEDs in terms of efficiency, their stability needs to be improved if they are to be applied in consumer electronics. When perovskite-based LEDs were first developed, they had a lifetime of just a few seconds. The LEDs developed in the current research have a half-life that is close to 50 hours — a huge improvement, but still inadequate for the lifetimes required for commercial applications.

University of Cambridge –

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