Project uses graphene acid to remove heavy metals from water
Researchers at Graphene Flagship associated member, Palacký University Olomouc in the Czech Republic, have shown graphene decorated with carboxylic groups extract has the potential to remove different types of metallic pollutant from water. Funded by a European Research Council (ERC) consolidator grant, the Partnering Project 2D-CHEM has the potential to solve one of the largest water challenges – pollution by heavy metals.
The World Health Organization estimates half of the world’s population will be living in water-stressed areas by 2025, and heavy metal contamination is among the primary threats to aquatic ecosystems and human health. Yet, the most economically advantageous method for metal removal from water is sorption, the chemical process of attaching one substance to another.
However, current sorption technologies are often inefficient in capturing heavy metals in water. As part of the Graphene Flagship’s efforts, the project has succeeded in producing a sorbent with graphene acid, an ultra-thin organic acid that offers excellent biocompatibility, conductivity and dispersibility in water.
The discovery comes after years of working on strategies to chemically synthesise graphene derivatives, which cannot be obtained by direct functionalisation of graphene itself. The researchers prepared graphene acid starting from fluorographene, using a technique developed at the Graphene Flagship associated member, Palacký University Olomouc, by replacing fluorine with other chemical elements to obtain the desired graphene derivative.
For example, graphene acid was prepared via a two-step process. Firstly, fluorographene was transformed into fluorine-free cyanographene and, secondly, it was hydrolysed to graphene acid.
“In principle, we can introduce any group to the surface of graphene, such as carboxyl, amino, sulfhydryl and hydroxyl groups,” said Michal Otyepka, 2D-CHEM leader and Head of the Regional Centre of Advanced Technology and Materials (RCPTM). “This creates new materials that can be employed in a wide spectrum of applications, ranging from metal extraction, electrochemical sensing, magnetism, catalysis and energy storage.”
Researchers reported that graphene acid-based water sorbents bind and capture heavy metals with high affinity, without leaching. In addition, the sorbent works in the presence of other ions, which are naturally found in drinking water, and can be reused after pH treatment without loss of performance.
The research also showed that this graphene acid-based sorbent not only can remove heavy metals from contaminated waters, but can also serve to extract noble metals, such as palladium, gallium or indium. The supply of noble metals on the planet is limited, and its inexpensive and efficient separation from waters provides enormous industrial opportunities.
“By improving the effectiveness of graphene-based sorbents, the 2D-CHEM project has made an important step toward the availability and sustainable management of water and sanitation for all,” added Yuri Svirko from Graphene Flagship Associated Member University of Eastern Finland, Partnering Division leader. “The latter also offers an attractive opportunity for noble metal recovery and catalysts reusability with zero losses in performance.”
References
Chronopoulos, Demetrios D., et al. “Chemistry, properties, and applications of fluorographene.” Applied materials today 9 (2017): 60-70. www.sciencedirect.com/science/article/pii/S2352940717301129?via%3Dihub
Bakandritsos, Aristides, et al. “Cyanographene and graphene acid: emerging derivatives enabling high-yield and selective functionalization of graphene.” ACS nano 11.3 (2017): 2982-2991. https://pubs.acs.org/doi/10.1021/acsnano.6b08449
Kolařík, Jan, et al. “Carboxylated Graphene for Radical-Assisted Ultra-Trace-Level Water Treatment and Noble Metal Recovery.” ACS nano 15.2 (2021): 3349-3358. https://pubs.acs.org/doi/abs/10.1021/acsnano.0c10093
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