The route to cleaner e-cars – coupling perovskite solar cells
The research, published in the Aug. 27 issue of Nature Communications, creates opportunities for cleaner transportation and novel home power sources.
"We found the right match between the solar cell and battery," explained Liming Dai, the Kent Hale Smith Professor of macromolecular science and engineering and leader of the research. "Others have used polymer solar cells to charge lithium batteries, but not with this efficiency."
In fact, the researchers say their overall photoelectric conversion and storage outperformed all other reported couplings of a photo-charging component with lithium-ion batteries, flow batteries or super-capacitors.
Perovskite solar cells have active materials with a crystalline structure identical to the mineral perovskite and are considered a promising new design for capturing solar energy. Compared to silicon-based cells, they convert a broader spectrum of sunlight into electricity.
Dai’s lab made multilayer solar cells, which increases their energy density, performance and stability. Testing showed that, as desired, the three layers convert into a single perovskite film.
By wiring four lab-sized cells, about 0.1 centimeter square each, in series, the researchers further increased the open circuit voltage. The solar-to-electric power conversion efficiency was 12.65 percent.
To charge button-sized lithium-ion batteries, they used a lithium-ion-phosphate cathode and a lithium-titanium-oxide anode. The photoelectric conversion and storage efficiency was 7.8 percent. Through 10 photo-charge/galvanostatic (steady current) discharge cycles lasting nearly 18 hours, the technology maintained almost identical discharge/charge curves over all cycles, showing high cycling stability and compatibility of the components.
"We envision, in the not too distant future, this is a system that you could have at home to refuel your car and, eventually, because perovskite solar cells can be made as a flexible film, they would be on the car itself," said Jiantie Xu, who, with Yonghua Chen, is an equally contributing first author of the study. Both are macromolecular science and engineering research associates in Case School of Engineering.
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