MIT researchers beat ITO with flexible organic conductive coating

November 25, 2019 //By Julien Happich
conductive coating
MIT researchers have improved on a PEDOT-based transparent, conductive coating material to compete with ITO on flexibility, conductivity and transparency.

In today’s touchscreens, the most widely used transparent conductor is indium titanium oxide (ITO) but the material is quite brittle and can crack after a period of use. So researchers all around the world are looking for more flexible metal or organic alternatives, but so far, the proposed films were either less transparent or less conductive than ITO, or more costly (when using silver nanowires).

In a study published in Science Advances under the title “Tuning, optimization, and perovskite solar cell device integration of ultrathin poly(3,4-ethylene dioxythiophene) films via a single-step all-dry process”, the researchers improved a flexible version of a transparent, conductive material they had designed two years ago, improving on its optical transparency and electrical conductivity.

The combined transparency and conductivity is measured in units of Siemens per centimeter. ITO ranges from 6,000 to 10,000. Although the new material was measured at 3,000, it is more flexible and could be applied directly to a large-scale, roll-to-roll industrial scale manufacturing process.

The organic polymer is deposited in an ultrathin layer just a few nanometers thick, using a process called oxidative chemical vapor deposition (oCVD), whereby the structure of the tiny crystals that form the polymer are all perfectly aligned horizontally, giving the material its high conductivity. Additionally, the oCVD method can decrease the stacking distance between polymer chains within the crystallites, which also enhances electrical conductivity.

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